Acid-Base Interactions Of Nicotine And Pyridine On Surfaces

TitleAcid-Base Interactions Of Nicotine And Pyridine On Surfaces
Publication TypeConference Paper
Year of Publication2005
AuthorsHugo Destaillats, Brett C Singer, Sharon K Lee, Lara A Gundel
Conference NameProceedings of the 10th International Conference on Indoor Air Quality and Climate - Indoor Air 2005
PublisherTsinghua University Press
Conference LocationBeijing, China
Keywordsacid-base, Environmental Chemistry, Exposure and Risk Group, indoor environment department, nicotine, pyridine, sorption, surface materials, volatile organic compounds
Abstract

Two different experimental approaches were employed to gain insight into the molecular interactions of nicotin e and pyridine with simple and well-characterized materials. We investigated nicotine desorption from Teflon and cotton surfaces in a flow chamber experiment and developed an ATR-FTIR spectrophotometric method to study the molecular association of pyridine with materials representative of certain indoor surfaces (cellulose and gypsum). The experimental results suggest the presence of two sorptive states for volatile amines. Spectroscopic evidence for acid-base interactions with surfaces is consistent with the observed desorption behavior.

LBNL Report Number

LBNL-57050